Carbon radicals are attractive intermediates for organic synthesis because of their diversity and high reactivities. In this research, we realized radical C-C bond formation reactions using alcohols as straightforward carbon radical precursors. We used a newly developed low-valent titanium reagent to cleave the C-O bonds of benzyl alcohol derivatives to generate the corresponding carbon radicals. This method was successfully applied to radical coupling reactions with several electron-deficient alkenes.
from Top Technology News -- ScienceDaily https://www.sciencedaily.com/releases/2018/11/181102095507.htm
from Top Technology News -- ScienceDaily https://www.sciencedaily.com/releases/2018/11/181102095507.htm
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